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1) at the head of a convent or nunnery (abbess)

2) at the head of an abbey or monastery (abbot)

3) a person at the head of a government department; to give help or service to a person, her or his needs (minister)

Synonyms
UK
US
Meaning:
ahead

in front, in advance, (of a person, thing)

in front or advance of

AT THE HEAD as in Wiktionary
AT THE HEAD as in Wikipedia